Heavy metal stabilization remediation in polluted soils with stabilizing materials: a review

The remediation of soil contaminated by heavy metals has long been a concern of academics. This is due to the fact that heavy metals discharged into the environment as a result of natural and anthropogenic activities may have detrimental consequences for human health, the ecological environment, the economy, and society. Metal stabilization has received considerable attention and has shown to be a promising soil remediation option among the several techniques for the remediation of heavy metal-contaminated soils. This review discusses various stabilizing materials, including inorganic materials like clay minerals, phosphorus-containing materials, calcium silicon materials, metals, and metal oxides, as well as organic materials like manure, municipal solid waste, and biochar, for the remediation of heavy metal-contaminated soils. Through diverse remediation processes such as adsorption, complexation, precipitation, and redox reactions, these additives efficiently limit the biological effectiveness of heavy metals in soils. It should also be emphasized that the effectiveness of metal stabilization is influenced by soil pH, organic matter content, amendment type and dosage, heavy metal species and contamination level, and plant variety. Furthermore, a comprehensive overview of the methods for evaluating the effectiveness of heavy metal stabilization based on soil physicochemical properties, heavy metal morphology, and bioactivity has also been provided. At the same time, it is critical to assess the stability and timeliness of the heavy metals' long-term remedial effect. Finally, the priority should be on developing novel, efficient, environmentally friendly, and economically feasible stabilizing agents, as well as establishing a systematic assessment method and criteria for analyzing their long-term effects.