Fabrication of a SnO₂-Sb electrode with TiO₂ nanotube array as the middle layer for efficient electrochemical...

Efficient, stable, and easily producible electrodes are useful for treating dye wastewater through electrochemical oxidation. In this study, an Sb-doped SnO₂ electrode with TiO₂ nanotubes as the middle layer (TiO₂-NTs/SnO₂-Sb) was prepared through an optimized electrodeposition process. Analyses of the coating morphology, crystal structure, chemical state, and electrochemical properties revealed that tightly packed TiO₂ clusters provided a larger surface area and more contact points, which is conducive to reinforcing the binding of SnO₂-Sb coatings. Compared with a Ti/SnO₂-Sb electrode without a TiO₂-NT interlayer, the catalytic activity and stability of the TiO₂-NTs/SnO₂-Sb electrode significantly improved (P < 0.05), as reflected by the 21.8% increase in the amaranth dye decolorization efficiency and 200% increase in the service life. The effects of current density, pH, electrolyte concentration, initial amaranth concentration, and the interaction between various combinations of parameters on the electrolysis performance were investigated. Based on response surface optimization, the maximum decolorization efficiency of the amaranth dye could reach 96.2% within 120 min under the following set of optimized parameter values: 50 mg L^-1 amaranth concentration, 20 mA cm^-2 current density, and 5.0 pH. A potential degradation mechanism of the amaranth dye was proposed based on the experimental results of a quenching test, ultraviolet-visible spectroscopy, and high-performance liquid chromatography-mass spectrometry. This study provides a more sustainable method for fabricating SnO₂-Sb electrodes with TiO₂-NT interlayers to treat refractory dye wastewater.