Turbostratic Lattice and Electronegativity Modification Jointly Enabled an Ultra-High-Rate and Long-Lived Carbon...

Potassium-ion batteries (PIBs) are considered as a promising technology alternative to lithium-ion batteries due to more abundance of potassium than lithium and a lower redox potential of K/K⁺ than that of Na/Na⁺. The critical limitation in PIBs is the electrode with poor rate capability and cycling stability induced by the sluggish reaction kinetics and large volume change during potassiation and depotassiation. In this work, we report a turbostratic lattice iodine-doped carbon (TLIC) nanosheet as an advanced innovative anode for PIBs displaying fast charge/discharge and electrode stability. The turbostratic lattice caused by doping of large-sized iodine and the unique charge transfer between iodine/carbon atoms creates more active sites and a shorter transport distance for K ions, improves the electrochemical activity, promotes rapid ion diffusion, and enhances pseudocapacitive behavior. The TLIC exhibits a high capacity of 433.5 mAh g^-1 at 50 mA g^-1, an ultrahigh rate capability of 162.1 mAh g^-1 at 20 A g^-1, and an excellent capacity retention of ∼96% (206 mAh g^-1) after 4000 cycles. The combination of turbostratic lattice and pseudocapactive storage is an effective approach to designing carbon electrodes with the transformational performance of high capacity, rate performance, and long lifetime for practical applications of PIBs.