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Updated: Aug 6, 2025

Screening of Coatings for an All-Solid-State Battery Using In Situ Transmission Electron Microscopy
Published on: January 20, 2023
Transition-metal interdiffusion and solid electrolyte poisoning in all-solid-state batteries revealed by cryo-TEM
Ruizhuo Zhang1, Florian Strauss1, Lin Jiang2
1Battery and Electrochemistry Laboratory, Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, Eggenstein-Leopoldshafen 76344, Germany. florian.strauss@kit.edu.
Abstract:
Using scanning transmission electron microscopy, along with electron energy loss spectroscopy, under cryogenic conditions, we demonstrate transition-metal dissolution from a layered Ni-rich oxide cathode material and subsequent diffusion into the bulk of a lithium thiophosphate solid electrolyte during electrochemical cycling. This problem has previously only been considered for liquid-electrolyte-based batteries.
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