Selective and effective oxidation of ammonium to dinitrogen in MgO/Na₂SO₃/K₂S₂O₈ system

The oxidation of ammonium (NH₄⁺) to dinitrogen (N₂) with high selectivity and high efficiency is still a challenge. Herein, a novel sunlight induced persulfate (PS)-based AOPs process (MgO/Na₂SO₃/PS/hv) was proposed by introducing solid base (MgO) and hydrated electron (e_aq^-), to selectively oxidize NH₄⁺ to N₂, with high selectivity and high efficiency at a wide range of pH value. The deprotonation of NH₄⁺ into NH₃ by MgO and the generation of •OH and SO₄^-• by PS activation were responsible for the high efficiency of NH₄⁺ oxidation. The buffering capacity provided by MgO to proton released from PS activation made the NH₄⁺ oxidation possible at a wide pH range. The e_aq^- from the Na₂SO₃/hv process was the main active specie to reduce NO₂^-and NO₃^- (NO_x^-) into N₂, responsible for high N₂ selectivity of NH₄⁺ oxidation. 100% NH₄⁺ could be oxidized within 30 min, and N₂ selectivity exceeded 96% at the initial pH range of 3-11 and the initial concentration of NH₄⁺ of 30 mg N/L. This work could offer an efficient AOPs process for selective NH₄⁺ oxidation, which is promising for the chemical denitrification of wastewater ….