A study to characterize the lead isotopic fingerprint in PM_2.5 emitted from incense stick and cigarette burning

The incense sticks and cigarettes burning are key sources of particulate matter with a diameter of ≤ 2.5 μm (PM_2.5) in indoor and outdoor air. While lead (Pb) isotope ratios provide valuable insights into the origin of particle pollution, their applicability for investigating these source remains unclear. The Pb isotope ratios in the PM_2.5 emitted from these two sources were analyzed, and effects of brands or nicotine contents on the ratios were assessed. In addition, As, Cr, and Pb were analyzed to investigate whether Pb isotope ratios can serve as an indicator for the source investigation of these metals. We found that average ratios of ²⁰⁶Pb/²⁰⁴Pb, ²⁰⁶Pb/²⁰⁷Pb, and ²⁰⁸Pb/²⁰⁷Pb in cigarettes were heavier than those in incense sticks. Scatter plots of Pb isotope ratios indicated an overlap of values for incense sticks or cigarettes linked to different brands, in that ratios for cigarettes with high nicotine content were heavier than for those with low nicotine content. Scatter plots of As, Cr, or Pb concentration against Pb isotope ratios clearly distinguished the effects of cigarette burning versus incense sticks with respect to PM_2.5 of these metals. Results indicate that brand differences did not affect the determination of PM_2.5 in these two sources. We suggest that Pb isotope ratios can be a useful tool in investigating the influence of incense sticks and of cigarettes (with high or low nicotine content) burning to PM_2.5 and associated metals.