D-π-A array structure of Bi₄Ti₃O₁₂-triazine-aldehyde group benzene skeleton for enhanced photocatalytic uranium (VI)...

Photocatalytic reduction of U^VI to U^IV can help remove U from the environment and thus reduce the harmful impacts of radiation emitted by uranium isotopes. Herein, we first synthesized Bi₄Ti₃O₁₂ (B1) particles, then B1 was crosslinked with 6-chloro-1,3,5-triazine-diamine (DCT) to afford B2. Finally, B3 was formed using B2 and 4-formylbenzaldehyde (BA-CHO) to investigate the utility of the D-π-A array structure for photocatalytic U^VI removal from rare earth tailings wastewater. B1 lacked adsorption sites and displayed a wide band gap. The grafted triazine moiety in B2 introduced active sites and narrowed the band gap. Notably, B3, a Bi₄Ti₃O₁₂ (donor)-triazine unit (π-electron bridge)-aldehyde benzene (acceptor) molecule, effectively formed the D-π-A array structure, which formed multiple polarization fields and further narrowed the band gap. Therefore, U^VI was more likely to capture electrons at the adsorption site of B3 and be reduced to U^IV due to energy level matching effects. U^VI removal capacity of B3 under simulated sunlight was 684.9 mg g^-1, 2.5 times greater than B1 and 1.8 times greater than B2. B3 was still active after multiple reaction cycles, and U^VI removal from tailings wastewater reached 90.8%. Overall, B3 provides an alternative design scheme for enhancing photocatalytic performance.