SO₂-Driven In Situ Formation of Superstable Hg₃Se₂Cl₂ for Effective Flue Gas Mercury Removal

Flue gas mercury removal is mandatory for decreasing global mercury background concentration and ecosystem protection, but it severely suffers from the instability of traditional demercury products (e.g., HgCl₂, HgO, HgS, and HgSe). Herein, we demonstrate a superstable Hg₃Se₂Cl₂ compound, which offers a promising next-generation flue gas mercury removal strategy. Theoretical calculations revealed a superstable Hg bonding structure in Hg₃Se₂Cl₂, with the highest mercury dissociation energy (4.71 eV) among all known mercury compounds. Experiments demonstrate its unprecedentedly high thermal stability (>400 °C) and strong acid resistance (5% H₂SO₄). The Hg₃Se₂Cl₂ compound could be produced via the reduction of SeO₃^2- to nascent active Se⁰ by the flue gas component SO₂ and the subsequent combination of Se⁰ with Hg⁰ and Cl^- ions or HgCl₂. During a laboratory-simulated experiment, this Hg₃Se₂Cl₂-based strategy achieves >96% removal efficiencies of both Hg⁰ and HgCl₂ enabling nearly zero Hg⁰ re-emission. As expected, real mercury removal efficiency under Se-rich industrial flue gas conditions is much more efficient than Se-poor counterparts, confirming the feasibility of this Hg₃Se₂Cl₂-based strategy for practical applications. This study sheds light on the importance of stable demercury products in flue gas mercury treatment and also provides a highly efficient and safe flue gas demercury strategy.