Cooperative effect of slow-release ferrous and phosphate for simultaneous stabilization of As, Cd and Pb in soil

The different chemical behavior of anionic As and cationic Cd and Pb makes the simultaneous stabilization of soils contaminated with arsenic (As), cadmium (Cd), and lead (Pb) challenging. The use of soluble, insoluble phosphate materials and iron compounds cannot simultaneously stabilize As, Cd, and Pb in soil effectively due to the easy re-activation of heavy metals and poor migration. Herein, we propose a new strategy of "cooperatively stabilizing Cd, Pb, and As with slow-release ferrous and phosphate". To very this theory, we developed ferrous and phosphate slow-release materials to simultaneously stabilize As, Cd, and Pb in soil. The stabilization efficiency of water-soluble As, Cd and Pb reached 99% within 7d, and the stabilization efficiencies of NaHCO₃-extractable As, DTPA-extractable Cd and Pb reached 92.60%, 57.79% and 62.81%, respectively. The chemical speciation analysis revealed that soil As, Cd and Pb were transformed into more stable states with the reaction time. The proportion of residual fraction of As, Cd, and Pb increased from 58.01% to 93.82%, 25.69 to 47.86%, 5.58 to 48.54% after 56 d, respectively. Using ferrihydrite as a representative soil component, the beneficial interactions of phosphate and slow-release ferrous material in stabilizing Pb, Cd, and As were demonstrated. The slow-release ferrous and phosphate material reacted with As and Cd/Pb to form stable ferrous arsenic and Cd/Pb phosphate. Furthermore, the slow-release phosphate converted the adsorbed As into dissolved As, then the dissolved As reacted with released ferrous to form a more stable form. Concurrently, As, Cd and Pb were structurally incorporated into the crystalline iron oxides during the ferrous ions-catalyzed transformation of amorphous iron (hydrogen) oxides. The results demonstrates that the use of slow-release ferrous and phosphate materials can aid in the simultaneous stabilization of As, Cd, and Pb in soil.