Effect of Functional Group Modifications on the Photocatalytic Performance of g-C₃ N₄

In recent years, photocatalysis has received increasing attention in alleviating energy scarcity and environmental treatment, and graphite carbon nitride (g-C₃ N₄ ) is used as an ideal photocatalyst. However, it still remains numerous challenges to obtain the desirable photocatalytic performance of intrinsic g-C₃ N₄ . Functional group functionalization, formed by introducing functional groups into the bulk structure, is one of the common modification techniques to modulate the carrier dynamics and increases the number of active sites, offering new opportunities to break the limits for structure-to-performance relationship of g-C₃ N₄ . Nevertheless, the general overview of the advance of functional group modification of g-C₃ N₄ is less reported yet. In order to better understand the structure-to-performance relationship at the molecular level, a review of the latest development of functional group modification is urgently needed. In this review, the functional group modification of g-C₃ N₄ in terms of structures, properties, and photocatalytic activity is mainly focused, as well as their mechanism of reaction from the molecular level insights is explained. Second, the recent progress of the application of introducing functional groups in g-C₃ N₄ is introduced and examples are given. Finally, the difficulties and challenges are presented, and based on this, an outlook on the future research development direction is shown.