Developing aerogel surfaces via switchable-hydrophilicity tertiary amidine coating for improved oil recovery

Blanket aerogels (i.e., Cabot™ Thermal Wrap® (TW) and Aspen™ Spaceloft® (SL)) with surfaces that have controllable wettability are promising advanced materials for oil recovery applications, where high oil uptake during deployment could be coupled with high oil release to enable reusability of recovered oil. The study presented here details the preparation of CO₂-switchable aerogel surfaces through the application of switchable tertiary amidine (i.e., tributylpentanamidine (TBPA)) onto aerogel surfaces using drop casting, dip coating, and physical vapor deposition techniques. TBPA is synthesized via two step processes: (1) synthesis of N, N-dibutylpentanamide, (2) synthesis of N, N-tributylpentanamidine. The deposition of TBPA is confirmed by X-ray photoelectron spectroscopy. Our experiments revealed that surface coating of TBPA onto aerogel blankets was partially successful within limited set of process conditions (e.g., 290 ppm CO₂ and 5500 ppm humidity for PVD, 106 ppm CO₂ and 700 ppm humidity for drop casting and dip coating), but that the post-aerogel modification strategies yielded poor, heterogeneous reproducibility. Overall, more than 40 samples were tested for their switchability in the presence of CO₂ and water vapor, respectively, and the success rate was 6.25 %, 11.7 % and 18 % for PVD, drop casting, and dip coating, respectively. The most likely reasons for unsuccessful coating onto aerogel surfaces are: (1) the heterogeneous fiber structure of the aerogel blankets, (2) poor distribution of the TBPA over the aerogel blanket surface.