Enhancing lead immobilization by biochar: Creation of "surface barrier" via bio-treatment

The long-term effectiveness of heavy metal immobilization is always a concern. This study proposes a completely novel approach to enhance the stability of heavy metals by combined biochar and microbial induced carbonate precipitation (MICP) technology, to create a "surface barrier" of CaCO₃ layer on biochar after lead (Pb²⁺) immobilization. Aqueous sorption studies and chemical and micro-structure tests were used to verify the feasibility. Rice straw biochar (RSB700) was produced at 700 °C, which shows high immobilization capacity of Pb²⁺ (maximum of 118 mg g^-1). But the stable fraction only accounts for 4.8% of the total immobilized Pb²⁺ on biochar. After MICP treatment, the stable fraction of Pb²⁺ significantly increased to a maximum of 92.5%. Microstructural tests confirm the formation of CaCO₃ layer on biochar. The CaCO₃ species are predominantly calcite and vaterite. Higher Ca²⁺ and urea concentrations in cementation solution resulted in higher CaCO₃ yield but lower Ca²⁺ utilization efficiency. The main mechanism of the "surface barrier" to enhance Pb²⁺ stability on biochar was likely the encapsulation effect: it physically blocked the contact between acids and Pb²⁺ on biochar, and chemically buffer the acidic attack from the environment. The performance of the "surface barrier" depends on both the yield of CaCO₃ and their distribution uniformity on biochar's surface. This study shed lights on the potential application of the "surface barrier" strategy combining biochar and MICP technologies for enhanced heavy metal immobilization.