Nanoparticle-Enhanced PVDF Flat-Sheet Membranes for Seawater Desalination in Direct Contact Membrane Distillation

In this study, hydrophobic functionalized carbon nanotubes (fCNTs) and silica nanoparticles (fSiO₂NPs) were incorporated into polyvinylidene fluoride (PVDF) flat-sheet membranes to improve their performance in membrane distillation (MD). The performance of the as-synthesized membranes was evaluated against commercial reference polytetrafluoroethylene (PTFE) flat-sheet membranes. The water contact angle (WCA) and liquid entry pressure (LEP) of the PVDF membrane were compromised after incorporation of hydrophilic pore forming polyvinylpyrrolidone (PVP). These parameters were key in ensuring high salt rejections in MD processes. Upon incorporation of fCNTS and fSiO₂NPs, WCA and LEP improved to 103.61° and 590 kPa, respectively. Moreover, the NP additives enhanced membrane surface roughness. Thus, an increase in membrane roughness improved WCA and resistance to membrane wetting. High salt rejection (>99%) and stable fluxes (39.77 kg m^-2 h^-1) were recorded throughout a 3 h process evaluation where 3.5 wt% NaCl solution was used as feed. These findings were recorded at feed temperature of 60 ℃. Evidently, this study substantiated the necessity of high feed temperatures towards high rates of water recovery.