Polydimethylsiloxane/Magnesium Oxide Nanosheet Mixed Matrix Membrane for CO₂ Separation Application

Carbon dioxide (CO₂) concentration is now 50% higher than in the preindustrial period and efforts to reduce CO₂ emission through carbon capture and utilization (CCU) are blooming. Membranes are one of the attractive alternatives for such application. In this study, a rubbery polymer polydimethylsiloxane (PDMS) membrane is incorporated with magnesium oxide (MgO) with a hierarchically two-dimensional (2D) nanosheet shape for CO₂ separation. The average thickness of the synthesized MgO nanosheet in this study is 35.3 ± 1.5 nm. Based on the pure gas separation performance, the optimal loading obtained is at 1 wt.% where there is no observable significant agglomeration. CO₂ permeability was reduced from 2382 Barrer to 1929 Barrer while CO₂/N₂ selectivity increased from only 11.4 to 12.7, and CO₂/CH₄ remained relatively constant when the MMM was operated at 2 bar and 25 °C. Sedimentation of the filler was observed when the loading was further increased to 5 wt.%, forming interfacial defects on the bottom side of the membrane and causing increased CO₂ gas permeability from 1929 Barrer to 2104 Barrer as compared to filler loading at 1 wt.%, whereas the CO₂/N₂ ideal selectivity increased from 12.1 to 15.0. Additionally, this study shows that there was no significant impact of pressure on separation performance. There was a linear decline of CO₂ permeability with increasing upstream pressure while there were no changes to the CO₂/N₂ and CO₂/CH₄ selectivity.