Reduced Graphene Oxide/Waste-Derived TiO₂ Composite Membranes: Preliminary Study of a New Material for Hybrid...

This work reports the preliminary results of the development of composite self-assembling membranes obtained by the combination of reduced graphene oxide (rGO) with commercial Degussa P25 titanium dioxide (TiO₂). The purpose is to demonstrate the possibility of combining, in the same self-standing material, the capability to treat wastewater containing both inorganic and organic pollutants by exploiting the established ability of rGO to capture metal ions together with that of TiO₂ to degrade organic substances. Moreover, this study also investigates the potential photocatalytic properties of tionite (TIO), to demonstrate the feasibility of replacing commercial TiO₂ with such waste-derived TiO₂-containing material, fulfilling a circular economy approach. Thus, rGO-TiO₂ and rGO-TIO composite membranes, 1:1 by weight, were prepared and characterized by SEM-EDX, XRD, thermogravimetry, as well as by Raman and UV-Vis spectroscopies to verify the effective and homogeneous integration of the two components. Then, they were tested towards 3-mg L^-1 aqueous synthetic solutions of Fe³⁺ and Cu²⁺ ions to evaluate their metal adsorption ability, with values of the order of 0.1-0.2 mmol g_membrane^-1, comparable or even slightly higher than those of pristine rGO. Finally, the ability of the composites to degrade a common organic pesticide, i.e., Imidacloprid^®, was assessed in preliminary photocatalysis experiments, in which maximum degradation efficiencies of 25% (after 3 h) for rGO-TiO₂ and of 21% (after 1 h) for rGO-TIO were found. The result of tionite-containing membranes is particularly promising and worthy of further investigation, given that the anatase content of tionite is roughly 1/6 of the one in commercial TiO₂.