In Situ Nanofibrillar Polypropylene-Based Composite Microcellular Foams with Enhanced Mechanical and Flame-Retardant...

With the increasing demand for plastic components, the development of lightweight, high strength and functionalized polypropylene (PP) from a cost-effective and environmentally friendly process is critical for resource conservation. In situ fibrillation (INF) and supercritical CO₂ (scCO₂) foaming technology were combined in this work to fabricate PP foams. Polyethylene terephthalate (PET) and poly(diaryloxyphosphazene)(PDPP) particles were applied to fabricate in situ fibrillated PP/PET/PDPP composite foams with enhanced mechanical properties and favorable flame-retardant performance. The existence of PET nanofibrils with a diameter of 270 nm were uniformly dispersed in PP matrix and served multiple roles by tuning melt viscoelasticity for improving microcellular foaming behavior, enhancing crystallization of PP matrix and contributing to improving the uniformity of PDPP's dispersion in INF composite. Compared to pure PP foam, PP/PET(F)/PDPP foam exhibited refined cellular structures, thus the cell size of PP/PET(F)/PDPP foam was decreased from 69 to 23 μm, and the cell density increased from 5.4 × 10⁶ to 1.8 × 10⁸ cells/cm³. Furthermore, PP/PET(F)/PDPP foam showed remarkable mechanical properties, including a 975% increase in compressive stress, which was attributed to the physical entangled PET nanofibrils and refined cellular structure. Moreover, the presence of PET nanofibrils also improved the intrinsic flame-retardant nature of PDPP. The synergistical effect of the PET nanofibrillar network and low loading of PDPP additives inhibited the combustion process. These gathered advantages of PP/PET(F)/PDPP foam make it promising for lightweight, strong, and fire-retardant polymeric foams.