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Updated: Aug 4, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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A Traceless Chiral Shift Reagent Based on Nonbonding Interactions with Single-Handed Helical

Takaya Fujie1, Takeshi Yamamoto1, Michinori Suginome1

  • 1Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto, 615-8510, Japan.

Angewandte Chemie (International Ed. in English)
|March 31, 2023
PubMed
Summary

A novel chiral shift reagent, poly(quinoxaline-2,3-diyl) (PQX), enables enantiomeric ratio determination using NMR spectroscopy. This reagent offers broad applicability and tunable shifts through nonbonding interactions with various analytes.

Keywords:
ChiralityHelical StructuresMolecular RecognitionNMR SpectroscopyNoncovalent Interactions

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