Selective photodimerization of acenaphthylene in polymersome nanoreactors
Sjoerd J Rijpkema1, Sam Vissers1, Daniela A Wilson1
1Department of Systems Chemistry, Institute for Molecules and Materials, Radboud University, Heyendaalseweg 135, 6525 AJ Nijmegen, The Netherlands. d.wilson@science.ru.nl.
Abstract:
PEG-b-PLA polymersomes are used as nanoreactors for the photodimerization of acenaphthylene (ACE), increasing reaction rate significantly. The reaction steered towards almost exclusive formation of anti product (94 : 6). This selectivity is remarkable, as other known systems commonly mediate formation of the syn product.
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