Compatibility and Interaction Mechanism between the C4F7N/CO2/O2 Gas Mixture and FKM and NBR
Ran Zhuo1,2,3, Junyi Chen4, Song Xiao4
1Electric Power Research Institute, China Southern Power Grid, Guangzhou 510623, China.
Abstract:
The C4F7N/CO2/O2 gas mixture received a great deal of attention for its potential use in eco-friendly gas-insulated equipment (GIE). The evaluation of the compatibility between C4F7N/CO2/O2 and sealing rubber is necessary and significant considering the high working pressure (0.14-0.6 MPa) of GIE. Herein, we explored the compatibility between C4F7N/CO2/O2 and fluororubber (FKM) and nitrile butadiene rubber (NBR) for the first time by analyzing the gas components, rubber morphology, elemental composition, and mechanical properties. The interaction mechanism of the gas-rubber interface was further investigated based on the density functional theory. We found that C4F7N/CO2/O2 is compatible with FKM and NBR at 85 °C, while the surface morphology changed at 100 °C, with white granular and agglomerated lumps appearing on FKM and multi-layer flakes being generated on NBR. The accumulation of the fluorine element occurred, and the compressive mechanical properties of NBR deteriorated after the gas-solid rubber interaction. Overall, the compatibility between FKM and C4F7N/CO2/O2 is superior, which could be employed as the sealing material for C4F7N-based GIE.
Related Concept Videos
02:19Physical Properties Affecting Solubility
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
02:56Intermolecular Forces and Physical Properties
03:13Intermolecular Forces
01:08Spin–Spin Coupling Constant: Overview
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must...
01:13¹H NMR: Complex Splitting
Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied...
01:13Olefin Metathesis Polymerization: Overview
Ruthenium-based Grubbs catalyst is the most commonly used catalyst for olefin metathesis polymerization. Grubbs catalyst consists...