Non-Toxic CuInS₂ /ZnS Colloidal Quantum Dots for Near-Infrared Light-Emitting Diodes

Ternary CuInS₂ quantum dots (QDs) with photoluminescence that is tunable from the visible to the near-infrared (NIR) region are promising light-emitters for consumer electronics due to the absence of toxic elements such as Pb, Cd, or As. Despite the compelling performance of visible-light-emitting CuInS₂ QDs, reports on NIR emission remain limited, with modest efficiencies at wavelengths beyond 900 nm. In this work, the facile synthesis of NIR-emitting CuInS₂ /ZnS QDs is reported. A combination of two sulfur precursors w as used in the synthesis, comprising 1-dodecanethiol (DDT) and hexamethyldisilathiane (HMDS). The reactive HMDS facilitates faster nucleation and leads to a higher density of emissive Cu-deficiency sites. The resulting QDs exhibit high photoluminescence quantum efficiency (PLQE) of 65% at a long emission wavelength of 920 nm. Using these QDs, NIR light-emitting diodes (LED) are fabricated, which attain an external quantum efficiency (EQE) of 8.2%. This efficiency is comparable to the best reported PbS and InAs QD LEDs, and the emission wavelength exceeds that of lead iodide perovskites. This work thus marks one of the first reports of efficient NIR LEDs based on environmentally benign CuInS₂ QDs and may open up promising new applications in consumer electronic products.