Induced bimetallic sulfide growth with reduced graphene oxide for high-performance sodium storage

Metal sulfide has been considered an ideal sodium-ion battery (SIB) anode material based on its high theoretical capacity. Nevertheless, the inevitable volume expansion during charge-discharge processes can lead to unsatisfying electrochemical properties, which limits its further large-scale application. In this contribution, laminated reduced graphene oxide (rGO) successfully induced the growth of SnCoS₄ particles and self-assembled into a nanosheet-structured SnCoS₄@rGO composite through a facile solvothermal procedure. The optimized material can provide abundant active sites and facilitate Na⁺ ion diffusion due to the synergistic interaction between bimetallic sulfides and rGO. As the anode of SIBs, this material maintains a high capacity of 696.05 mAh g^-1 at 100 mA g^-1 after 100 cycles and a high-rate capability of 427.98 mAh g^-1 even at a high current density of 10 A g^-1. Our rational design offers valuable inspiration for high-performance SIB anode materials.