Electrospun Fe doped TiO₂ fiber photocatalyst for efficient wastewater treatment

Water pollution caused by industrial wastewater is the most critical environmental problem in the world. Synthetic dyes are commonly used in various industries such as paper, plastic, printing, leather and textile for their ability to impact color. Complex composition, high toxicity and low biodegradability of dyes make them difficult to degrade which causes a substantial negative impact on overall ecosystems. To address this issue we synthesized TiO₂ fibers photocatalyst using the combination of sol-gel and electrospinning techniques to be used in the degradation of dyes which causes water pollution. We doped Fe in TiO₂ fibers to enhance the absorption in the visible region of the solar spectrum which will also help to increase the degradation efficiency. As synthesized pristine TiO₂ fibers and Fe doped TiO₂ fibers were analyzed using different characterization techniques such as X-ray diffraction, Scanning electron microscopy, Transmission electron microscopy, UV-Visible spectroscopy, X-ray photoelectron spectroscopy. 5% Fe doped TiO₂ fibers show excellent photocatalytic degradation activity for rhodamine B (99% degradation in 120 min). It can be utilized for degradation of other dye pollutants such as methylene blue, Congo red and methyl orange. It shows good photocatalytic activity (97%) even after 5 cycles of reuse. The radical trapping experiments reveals that holes, ^•O₂^- and ^•OH has a significant contribution in the photocatalytic degradation. Due to the robust fibrous nature of 5FeTOF the process of collection of photocatalysts was simple and without loss as compared to powder photocatalysts. This justifies our selection of electrospinning method of synthesis of 5FeTOF which is also useful for large scale production.