Understanding the copper-iridium nanocrystals as highly effective bifunctional pH-universal electrocatalysts for...

It is pivotal to develop an economical, effective, and stable catalyst to promote the oxygen/hydrogen evolution reaction (OER/HER) throughout pH electrolytes, as the demand for hydrogen energy will increase greatly with the future development. Herein, a series of Ir-Cu nanoparticle composite carbon (Ir_xCu_y/C) catalysts are successfully synthesized using ethylene glycol reduction. In addition, the structure, morphology and composition of the electrocatalysts were systematically characterized, and the OER/HER performance of the catalysts was also tested under different pH conditions. According to experimental findings, amorphous Ir₃Cu/C has superior competent performance to catalyze oxygen (O₂) production in alkaline and acidic environments. The comparatively low overpotentials required are 222 mV and 304 mV, respectively, while generating a current density of 10 mA cm^-2. The reduced amount of precious metal and the further improvement in activity and durability make Ir₃Cu/C an excellent noble metal-based electrocatalyst. Meanwhile, IrCu/C has significant electrocatalytic performance for the HER in acidic media.