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Electrochemical Roughening of Thin-Film Platinum Macro and Microelectrodes
Published on: June 30, 2019
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Studies on the Platinum Thick Film Sensor Conformally Written by Laser Micro-Cladding: Formability, Microstructure,
Yueyue Wang1, Taoyuan Ouyang1, Li Meng1
1Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Wuhan 430074, China.
ACS Applied Materials & Interfaces
|April 11, 2023
Summary
Laser micro-cladding (LMC) creates high-temperature platinum thick film sensors. This method optimizes sintering for improved adhesion and reduced resistivity, enabling high-performance temperature sensing.
Area of Science:
- Materials Science
- Sensor Technology
- Surface Engineering
Background:
- High-temperature sensors require robust fabrication methods.
- Platinum (Pt) films are crucial for accurate temperature sensing.
- Existing methods like sputtering have limitations in conformal integration.
Purpose of the Study:
- To investigate laser micro-cladding (LMC) for in situ preparation of high-temperature platinum (Pt) thick film sensors.
- To systematically study the formability, microstructure, sintering, and electrical properties of LMCed Pt films.
- To evaluate the performance of LMC-fabricated Pt resistance temperature detectors (RTDs) and thermocouples.
Main Methods:
- Laser micro-cladding (LMC) was employed to deposit Pt thick films.
- Systematic analysis of film properties including adhesion, microstructure, and electrical resistivity.
- Fabrication and testing of Pt RTD and Pt-Pt10%Rh thermocouple sensors.
- Comparison with sensors fabricated via direct DC magnetron sputtering deposition.
Main Results:
- Optimal laser power density (1.37 × 10^6 W·cm^-2) yielded Pt films with minimum resistivity (46 ± 2 μΩ·cm), good adhesion, and excellent conductive networks.
- LMC-fabricated Pt RTDs exhibited high linearity (0.9985) and a TCR of 2.46 × 10^-3/°C at 920 °C.
- LMC-fabricated Pt thermocouples showed high linearity (0.9905) and a Seebeck coefficient of 9.7 μV/°C.
- Performance surpassed that of sensors made by DC magnetron sputtering.
Conclusions:
- Laser micro-cladding is a viable technique for in situ fabrication of high-performance, conformal high-temperature Pt thick film sensors.
- LMC offers advantages over traditional methods for sensor integration.
- This technology enables the development of advanced temperature sensing solutions.

