Enhanced Efficiency and Stability of Novel Pseudo-ternary Polymer Solar Cells Enabled by a Conjugated Donor Block...

The recent breakthrough in power conversion efficiencies (PCEs) of polymer solar cells (PSCs) that contain an active layer of a ternary system has achieved values of 18-19%; this has sparked interest for further research. However, this system has difficulties in optimizing the composition and controlling the interaction between the three active materials. In this study, we investigated the use of a donor₁ (D₁)-donor₂ (D₂) conjugated block copolymer (CBP), PM6-b-TT, to replace the physical blend of two donors. PM6-b-TT, which exhibits an extended absorption range, was synthesized by covalently bonding PM6, a medium-band gap polymer, with PBDT-TT, a wide-band gap polymer. The blend films containing PM6-b-TT and Y6-BO acceptor, demonstrated excellent crystallinity and a film morphology favorable for PSCs. The corresponding pseudo-ternary PSC exhibited significantly higher PCE and thermal stability than the PM6:PBDT-TT-based ternary device. This study unambiguously demonstrates that the novel D₁-D₂ CBP strategy, combined with the conventional binary and ternary system advantages, is a promising material production strategy that can boost the performance of future PSCs.