Oxidation of Methanol and Dichloromethane on TiO₂-CeO₂-CuO, TiO₂-CeO₂ and TiO₂-CuO@VUKOPOR^®A Ceramic Foams

The application-attractive form of TiO₂, CeO₂ and CuO-based open-cell foam supported catalysts was designed to investigate their catalytic performance in oxidation of two model volatile organic compounds-methanol and dichloromethane. TiO₂-CeO₂, TiO₂-CuO and TiO₂-CeO₂-CuO catalysts as thin films were deposited on VUKOPOR^®A ceramic foam using a reverse micelles-controlled sol-gel method, dip-coating and calcination. Three prepared catalytic foams were investigated via light-off tests in methanol and dichloromethane oxidation in the temperature range of 45-400 °C and 100-500 °C, respectively, at GHSV of 11, 600 h^-1, which fits to semi-pilot/industrial conditions. TiO₂-CuO@VUKOPOR^®A foam showed the best catalytic activity and CO₂ yield in methanol oxidation due to its low weak Lewis acidity, high weak basicity and easily reducible CuO species and proved good catalytic stability within 20 h test. TiO₂-CeO₂-CuO@VUKOPOR^®A foam was the best in dichloromethane oxidation. Despite of its lower catalytic activity compared to TiO₂-CeO₂@VUKOPOR^®A foam, its highly-reducible -O-Cu-Ce-O- active surface sites led to the highest CO₂ yield and the highest weak Lewis acidity contributed to the highest HCl yield. This foam also showed the lowest amount of chlorine deposits.