Two-Dimensional Sb Modified TiO₂ Nanorod Arrays as Photoanodes for Efficient Solar Water Splitting

As one of the widely studied semiconductor materials, titanium dioxide (TiO₂) exhibits high photoelectrochemical (PEC) water-splitting performance as well as high chemical and photo stability. However, limited by a wide band gap and fast electron-hole recombination rate, the low solar-to-hydrogen conversion efficiency remains a bottleneck for the practical application of TiO₂-based photoelectrodes. To improve the charge separation and water oxidation efficiency of TiO₂ photoanodes, antimonene, a two-dimensional (2D) material obtained by liquid-phase exfoliation, was assembled onto TiO₂ nanorod arrays (TNRAs) by a simple drop-coating assembly process. PEC measurements showed that the resulting 2D Sb/TiO₂ photoelectrode displayed an enhanced photocurrent density of about 1.32 mA cm^-2 in 1.0 M KOH at 0.3 V vs. Hg/HgO, which is ~1.65 times higher than that of the pristine TNRAs. Through UV-Vis absorption and electrochemical impedance spectroscopy measurements, it was possible to ascribe the enhanced PEC performances of the 2D Sb/TiO₂ photoanode to increased absorption intensity in the visible light region, and improved interfacial charge-transfer kinetics in the 2D Sb/TiO₂ heterojunction, which promotes electron-hole separation, transfer, and collection.