Nanoshaped Cerium Oxide with Nickel as a Non-Noble Metal Catalyst for CO₂ Thermochemical Reactions

Four different nanoshapes of cerium dioxide have been prepared (polycrystals, rods, cubes, and octahedra) and have been decorated with different metals (Ru, Pd, Au, Pt, Cu, and Ni) by incipient wetness impregnation (IWI) and ball milling (BM) methods. After an initial analysis based on oxygen consumption from CO₂ pulse chemisorption, Ni-like metal, and two forms of CeO₂ cubes and rods were selected for further research. Catalysts were characterized using the Brunauer-Emmett-Teller formula (BET), X-ray spectroscopy (XRD), Raman spectroscopy, scanning electron microscopy (SEM), UV-visible spectrophotometry (UV-Vis), X-ray photoelectron spectroscopy (XPS), temperature programmed reduction (H₂-TPR) and CO₂ pulse chemisorption, and used to reduce of CO₂ into CO (CO₂ splitting). Adding metals to cerium dioxide enhanced the ability of CeO₂ to release oxygen and concomitant reactivity toward the reduction of CO₂. The effect of the metal precursor and concentration were evaluated. The highest CO₂ splitting value was achieved for 2% Ni/CeO₂-rods prepared by ball milling using Ni nitrate (412 µmol/g_cat) and the H₂ consumption (453.2 µmol/g_cat) confirms the good redox ability of this catalyst.