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Updated: Aug 3, 2025

Light-driven Enzymatic Decarboxylation
Published on: May 22, 2016
External Catalyst- and Additive-Free Photo-Oxidation of Aromatic Alcohols to Carboxylic Acids or Ketones Using Air/O2
Meng Xu1, Jinhua Ou1, Kejun Luo2
1School of Materials Science and Engineering, Hunan Institute of Technology, Hengyang 421002, China.
Abstract:
We present an environment-friendly and highly efficient method for the oxidation of aromatic alcohols to carboxylic acids or ketones in air via light irradiation under external catalyst-, additive-, and base-free conditions. The photoreaction system exhibits a wide substrate scope and the potential for large-scale applications. Most of the desired products are easily obtained via recrystallization and separation from low-boiling reaction medium acetone in good yields, and the products can be subsequent directly transformed without further purification.
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