All-solid-state Ti₃C₂T_x neutral symmetric fiber supercapacitors with high energy density and wide temperature range

All-solid-state Ti₃C₂T_x neutral symmetric fiber supercapacitors (PVA EGHG Ti₃C₂T_x FSCs) with high energy density and wide temperature range are constructed by using polyvinyl alcohol (PVA)-ethylene glycol hydrogel (EGHG)-sodium perchlorate (NaClO₄) as electrolyte and separator, and Ti₃C₂T_x fiber as electrodes. Ti₃C₂T_x fiber is prepared using 130 mg mL^-1 Ti₃C₂T_x nanosheet ink as an assembly unit in a coagulation bath of isopropyl alcohol (IPA) and distilled water with 5 wt% CaCl₂ by a wet spinning method. The prepared Ti₃C₂T_x fiber exhibits a specific capacity of 385 F cm^-3 and a capacitance retention of 94 % after 10,000 cycles in 1 M NaClO₄ electrolyte. The assembled PVA EGHG Ti₃C₂T_x FSCs deliver a specific capacitance of 41 F cm^-3, a volumetric energy density of 5 mWh cm^-3, and a capacitance retention of 92 % after 500 times continuous bending. Furthermore, it shows good flexibility and excellent capacitance over a wide temperature range of -40 to 40 °C and maintains its electrochemical performance under varying degrees of bending. This study provides a viable strategy for designing and assembling all-solid-state neutral symmetric fiber supercapacitors with high energy density and wide temperature range.