Related Experiment Video
Updated: Aug 2, 2025

Synthesis of Bimetallic Pt/Sn-based Nanoparticles in Ionic Liquids
Published on: August 23, 2018
Reactions of noble-metal oxides in ionic liquids near room temperature
Mareike Liebertseder1, Carsten Donsbach1, Claus Feldmann1
1Institute for Inorganic Chemistry, Karlsruhe Institute of Technology (KIT) Engesserstrasse 15 D-76131 Karlsruhe Germany claus.feldmann@kit.edu.
Abstract:
The reaction of Ag2O, Au2O3, and HgO with CuCl, CuI, AgCl, AgI, AuCl, and AuI in ionic liquids ([EMIm]Cl, [BMIm]Cl) near room temperature (20-80 °C) is evaluated and results in the new compounds (C8H14N2)CuCl, (C8H14N2)AgI, (C6H10N2)AuCl, [(C8H14N2)2Hg][CuCl3], [(C8H14N2)2Hg][AgCl3], and [EMIm][Ag2I2Cl]. Thereof, (C8H14N2)CuCl, (C8H14N2)AgI, (C6H10N2)AuCl, [(C8H14N2)2Hg][CuCl3], and [(C8H14N2)2Hg][AgCl3] are NHC complexes (NHC: N-heterocyclic carbene) with M-C bonds (M: Cu, Ag, Au, Hg). Whereas (C8H14N2)CuCl and (C8H14N2)AgI crystallize as single molecules, (C6H10N2)AuCl is dimerized via aurophilic interactions. [(C8H14N2)2Hg][CuCl3] and [(C8H14N2)2Hg][AgCl3] exhibit Hg atoms with two Hg-C bonds. Moreover, (C8H14N2)AgI shows intense green fluorescence at room temperature with a quantum yield of 44%, whereas all other compounds do not show any emission at room temperature. Finally, [EMIm][Ag2I2Cl] is not an NHC compound but contains ∞ 1[AgI1/2I2/4Cl1/2]- chains with infinite d10-d10 interaction of the silver atoms. The title compounds are characterized by single-crystal structure analysis, infrared spectroscopy, thermogravimetry, and fluorescence spectroscopy.
More Related Videos
11:04Synthesis of Ionic Liquid Based Electrolytes, Assembly of Li-ion Batteries, and Measurements of Performance at High Temperature
Published on: December 20, 2016
09:18Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications
Published on: June 21, 2017
Related Concept Videos
Alkali Metals
Table 1: Properties of the alkali metals
Properties of Transition Metals
Noble Gases
The elements in group 18 are noble gases (helium, neon, argon, krypton, xenon, and radon). They earned the name “noble” because they were assumed to be nonreactive since they have filled valence shells. In 1962, Dr. Neil Bartlett at the University of British Columbia proved this assumption to be false.
Reaction Mechanisms
For instance, the decomposition of ozone appears to follow a mechanism with two steps:
Chemical Reactions in Aqueous Solutions
Ionic Bonding and Electron Transfer