Surface Phenomena with the Participation of Sulfite Lignin under Pressure Leaching of Sulfide Materials

Searching for surfactants which can eliminate the occluding effect of molten elemental sulfur formed in the process of leaching sulfide ores under pressure (autoclave leaching) is relevant. However, the choice and use of surfactants are complicated by the harsh conditions of the autoclave process, as well as the insufficient knowledge of surface phenomena in their presence. This paper presents a comprehensive study of interfacial phenomena (adsorption, wetting, and dispersion) involving surfactants (using lignosulfonates as an example) and zinc sulfide/concentrate/elemental sulfur under conditions simulating sulfuric acid leaching of ores under pressure. The influence of concentration (C_LS 0.1-1.28 g/dm³), features of the molecular weight (M̅_w, 9.250-46.300 Da) composition of lignosulfates, temperature (10-80 °C), addition of sulfuric acid (CH₂SO₄ 0.2-10.0 g/dm³), and properties of solid-phase objects (surface charge, specific surface area, presence and diameter of pores) on surface phenomena at the liquid-gas and liquid-solid interfaces was revealed. It was found that with an increase in molecular weight and a decrease in the degree of sulfonation, the surface activity of lignosulfonates at the liquid-gas interface, as well as their wetting and dispersing activity with respect to zinc sulfide/concentrate increases. It has been found that an increase in temperature contributes to the compaction of the macromolecule of lignosulfonates, as a result of which their adsorption at the liquid-gas and liquid-solid interface in neutral media rises. It has been shown that the introduction of sulfuric acid into aqueous solutions increases the wetting, adsorption, and dispersing activity of lignosulfonates with respect to zinc sulfide. The latter is accompanied by a decrease in the contact angle θ (by 10 and 40°) and an increase in both the specific number of zinc sulfide particles (not less than 1.3-1.8 times) and the content of fractions with a size of -3.5 μm. It has been established that the functional effect of lignosulfonates under conditions simulating sulfuric acid autoclave leaching of ores is implemented through the adsorption-wedging mechanism.