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Related Concept Videos

Colloids and Suspensions01:17

Colloids and Suspensions

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles visible to the naked eye or seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. The suspended particles in a suspension settle out after some time of mixing. The separation of particles from a suspension is...
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Colloids03:22

Colloids

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Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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Colloidal precipitates01:09

Colloidal precipitates

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The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
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Anionic Chain-Growth Polymerization: Overview01:20

Anionic Chain-Growth Polymerization: Overview

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The polymerization process that involves carbanion as an intermediate is called anionic polymerization. It is also a type of addition or chain-growth polymerization. Anionic polymerization gets initiated by a strong nucleophile such as an organolithium or a Grignard reagent. The most commonly used initiator for anionic polymerization is butyl lithium. Monomers involved in anionic polymerization must possess a vinyl group bonded to one or two electron-withdrawing groups. For instance,...
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Step-Growth Polymerization: Overview01:03

Step-Growth Polymerization: Overview

3.6K
Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
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Polymer Classification: Crystallinity01:21

Polymer Classification: Crystallinity

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Unlike ionic or small covalent molecules, polymers do not form crystalline solids due to the diffusion limitations of their long-chain structures. However, polymers contain microscopic crystalline domains separated by amorphous domains.
Crystalline domains are the regions where polymer chains are aligned in an orderly manner and held together in proximity by intermolecular forces. For example, chains in the crystalline domains of polyethylene and nylon are bound together by van der Waals...
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Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
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Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures

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Polymer Colloids: Current Challenges, Emerging Applications, and New Developments.

Miren Aguirre1, Nicholas Ballard1,2, Edurne Gonzalez1

  • 1POLYMAT, Kimika Fakultatea, University of the Basque Country UPV/EHU, Joxe Mari Korta Zentroa, Tolosa Hiribidea 72, 20018 Donostia-San Sebastian, Spain.

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|April 17, 2023
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Summary
This summary is machine-generated.

Polymer colloids, synthesized via emulsion polymerization, face challenges in sustainability and environmental impact. Novel designs and unconventional processing unlock new applications for these versatile materials.

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Synthesis and Characterization of Supramolecular Colloids
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Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Colloid Science

Background:

  • Polymer colloids are versatile materials synthesized through water-based emulsion polymerization.
  • This method allows for efficient, large-scale production of colloidal particles with tunable properties.
  • Their commercial use is expanding across various applications.

Purpose of the Study:

  • To highlight key challenges in polymer colloid synthesis and application.
  • To explore the transition towards sustainable feedstocks and reduced environmental impact.
  • To discuss novel designs and unconventional processing for emerging applications.

Main Methods:

  • Review of current production and application challenges.
  • Analysis of features enabling novel polymer colloid design.
  • Examination of unconventional processing techniques leveraging colloidal properties.

Main Results:

  • Identified challenges in sustainable feedstock adoption and environmental impact reduction.
  • Highlighted design features for advanced polymer colloids.
  • Showcased innovative processing methods utilizing unique colloidal characteristics.

Conclusions:

  • Addressing sustainability is crucial for the future of polymer colloids.
  • Novel colloid design and processing are key to unlocking new application frontiers.
  • Emulsion polymerization remains a vital technique for scalable colloid production.