Enhanced CO Functionality on Carbon Papers Ensures Lowering Nucleation Delay of ALD for Ru towards Unprecedented
Sitaramanjaneya M Thalluri1,2, Jhonatan Rodriguez-Pereira1,2, Raul Zazpe1,2
1Central European Institute of Technology, Brno University of Technology, Purkynova 123, 61200, Brno, Czech Republic.
Abstract:
The success in lowering the nucleation delay for Atomic Layer Deposition (ALD) of Ru on carbon surfaces is mitigated by constructive pretreatments resulting enhancement of CO functionality. Treatment of the carbon papers (CP) allowed Ru species deposition for minimum number of ALD cycles (25 cycles) with good conformality. The development of electrocatalysts from single atoms to nanoparticles (NPs) on conductive supports with low metal loadings, thus improving performance, is essential in electrocatalysis. For alkaline hydrogen evolution reaction, ALD decorated CPs with Ru exhibit low onset potentials of ≈4.7 mV versus reversable hydrogen electrode (RHE) (at 10 mA cm-2 ) and a high turnover frequency of 1.92 H2 s-1 at 30 mV versus RHE. The Ru decorated CPs show comparable to higher catalytic activity than of Platinum (Pt) decorated CP also developed by ALD. The current representation of unfamiliar catalytic activities of Ru active centers developed by ALD, pave a bright and sustainable path for energy conversion reactions.
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