Reinforcement of resin-modified glass-ionomer cement with glass fiber and graphene oxide

To evaluate the effect of adding glass fiber and graphene oxide to a resin-modified glass ionomer cement (RMGIC).

Experimental RMGICs were prepared by adding separately and simultaneously glass fibers (5, 10, and 20 wt%) and graphene oxide (1, 3, and 5 wt%) to the powder of RMGIC with different ratios. The samples were examined under SEM and XRD. The surface roughness, flexural strength, Vickers microhardness, water sorption, and solubility were investigated. Data were analyzed using ANOVA and Tukey tests (p = 0.05).

Adding fiber and graphene oxide to RMCIS increased the surface roughness, flexural strength, and microhardness. The highest surface roughness value was obtained in the 20% fiber+5% graphene oxide adding group and the lowest in the control group (p < 0.05). The highest microhardness and flexural strength values were acquired in the 20% fiber-adding group and the lowest in the control group (p < 0.05). 10% and 20% fiber addition increased water sorption and solubility (p < 0.05). Adding 3%, 5% graphene oxide, and 20% fiber+5% graphene oxide reduced water sorption (p < 0.05). The highest water sorption was found in the 20% fiber-adding group and the lowest in the 5% graphene oxide and %20 fiber+5% graphene oxide-adding groups (p < 0.05). Graphene oxide alone and together with fiber did not affect the solubility (p > 0.05).

The results show that reinforcement of RMGIC with glass fiber and graphene oxide may improve the mechanical properties. But the glass fibers may cause more water sorption and solubility. Graphene oxide may decrease water sorption of RMGIC and fiber-reinforced RMGIC.