Cocatalyst loaded Al-SrTiO₃ cubes for Congo red dye photo-degradation under wide range of light

The continued pollution, waste, and unequal distribution of the limited amount of fresh water on earth are pushing the world into water scarcity crisis. Consequently, development of revolutionary, cost-effective, and efficient techniques for water purification is essential. Herein, molten flux method was used for the preparation of micro-sized Al-doped SrTiO₃ photocatalyst loaded with RhCr₂O₃ and CoOOH cocatalysts via simple impregnation method for the photo-assisted degradation of Congo red dye under UV and visible irradiation compared with P25 standard photocatalyst. In addition, photoelectrochemical analysis was conducted to reveal the separation and transfer efficiency of the photogenerated e^-/h⁺ pairs playing the key role in photocatalysis. SEM and TEM analyses revealed that both P25 and the pristine SrTiO₃ have spherical shapes, while Al-doped SrTiO₃ and the sample loaded with cocatalysts have cubic shapes with a relatively higher particle size reaching 145 nm. In addition, the lowest bandgap is due to Al⁺³ ion doping and excessive surface oxygen vacancies, as confirmed by both UV-Vis diffuse-reflectance and XPS analyses. The loading of the cocatalysts resulted in a change in the bandgap from n-type (pristine SrTiO₃ and Al-SrTiO₃) into p-type (cocatalyst loaded sample) as exhibited by Mott-Schottky plots. Besides, the cocatalyst-loaded sample exhibited good performance stability after 5 cycles of the photocatalytic removal of Congo red dye. OH^· radical was the primary species responsible for CR degradation as confirmed by experiments with radical scavengers. The observed performance of the prepared samples under both UV and visible light could foster the ongoing efforts towards more efficient photocatalysts for water purification.