Random walk model of mobility in glass formers

A mechanism responsible for the generic features of the mean squared displacement and the decay of the orientational autocorrelator of a molecule in a glass forming liquid is poorly understood, where such a mechanism would be critical for creating the theory of glass transition. A discrete random walk model is proposed where, instead of a straight line, a walk is along a tortuous path consisting of blocks of switchback ramps. Subdiffusive regime, short-term dynamic heterogeneity, and existence of the α- and β-relaxation processes emerge naturally from the model. The model suggests that slowing of the rate of relaxation may be due to an increase in the number of the switchback ramps per block rather than due to growth of an energy barrier as typically assumed.