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Dinuclear Mn(I) Complexes with Phosphido and Hydrido Bridges: Synthesis, Reactivity, and Hydrogenative Catalysis
David C Lacy1, Preshit C Abhyankar1
1Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260, USA.
Abstract:
A class of organomanganese hydrogenation catalysts was recently rediscovered. These are simple dinuclear Mn(I) carbonyl compounds with phosphido (PR2 - ) and hydrido (H- ) bridges. This class of compounds has been known since the 1960's, and they have rich coordination chemistry and reactivity. Given their recently discovered potential for catalytic applications, a fresh look at this class of compounds was necessary. Hence, this Review comprehensively covers the synthesis, reactivity, and catalysis of this interesting class of molecules.
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