Artificial Interphase Design Employing Inorganic-Organic Components for High-Energy Lithium-Metal Batteries

To increase the energy density of today's lithium batteries, it is necessary to develop an anode with higher energy density than graphite or carbon/silicon composites. Hence, research on metallic lithium has gained a steadily increasing momentum. However, the severe safety issues and poor Coulombic efficiency of this highly reactive metal hinder its practical application in lithium-metal batteries (LMBs). Herein, the development of an artificial interphase is reported to enhance the reversibility of the lithium stripping/plating process and suppress the parasitic reactions with the liquid organic carbonate-based electrolyte. This artificial interphase is spontaneously formed by an alloying reaction-based coating, forming a stable inorganic/organic hybrid interphase. The accordingly modified lithium-metal electrodes provide substantially improved cycle life to symmetric Li||Li cells and high-energy Li||LiNi_0.8Co_0.1Mn_0.1O₂ cells. For these LMBs, 7 μm thick lithium-metal electrodes have been employed while applying a current density of 1.0 mA cm^-2, thus highlighting the great potential of this tailored interphase.