V₂O₃@C Microspheres as the High-Performance Cathode Materials for Advanced Aqueous Zinc-Ion Storage

Vanadium oxides attract increasing research interests for constructing the cathode of aqueous zinc-ion batteries (ZIBs) because of high theoretical capacity, but the low intrinsic conductivity and unstable phase changes during the charge/discharge process pose great challenges for their adoption. In this work, V₂O₃@C microspheres were developed to achieve enhanced conductivity and improved stability of phase changes. Compounding vanadium oxides and conductive carbon through the in-situ carbonization led to significant improvement of the cathode materials. ZIBs prepared with V₂O₃@C cathodes produce a specific capacity of 420 mA h g^-1 at 0.2 A g^-1. A reversible capacity of 132 mA h g^-1 was achieved at 21.0 A g^-1. After 2000 cycles, the electrode could still deliver a capacity of 202 mA h g^-1 at the current of 5.0 A g^-1. Besides, the energy density of batteries constructed with the thus-prepared electrodes was about 294 W h kg^-1 at 148 W kg^-1 power. The in-situ compounding of V₂O₃ and carbon resulted in a microstructure that facilitated the stable phase transformation of ZnV₂O_5-·nH₂O (ZnVOH), which provided more Zn²⁺ storage activity than the original phase before electrochemical activation. Moreover, the in-situ compositing strategy presents a simple route to the development of ZIB cathodes with promising performance.