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Construction of Pd-based coordination cages with three geometrically distinct ligands
Ru-Jin Li1, Jean de Montmollin1, Farzaneh Fadaei-Tirani1
1Institut des Sciences et Ingénierie Chimiques, École Polytechnique Fédérale de Lausanne (EPFL), 1015 Lausanne, Switzerland. kay.severin@epfl.ch.
Abstract:
Three different dipyridyl ligands were combined with [Pd(CH3CN)4](BF4)2 to give mixtures of homo- and/or heteroleptic coordination cages. The three ligands were chosen so that one ligand shows a parallel orientation of the coordinate vectors, the second ligand a bent angle of 60°, and the third ligand a bent angle of 120°. We have identified ligand mixtures that give rise to integrative self-sorting, and we have characterized a heterotrileptic [Pd4L2L'2L''4]8+ cage by single crystal X-ray crystallography. The structural flexibility of ligands with alkynyl spacers was found to be of importance for the formation of heteroleptic complexes.
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