Direct Urea/H₂O₂ Fuel Cell with a Hierarchical Porous Nanoglass Anode for High-Efficiency Energy Conversion

Direct urea/H₂O₂ fuel cells (DUFCs) constitute a sustainable bifunctional energy conversion technique devoted to simultaneously eliminating environmental wastewater with urea and generating clean energy. However, exploring an efficient anode material for DUFCs still remains a huge challenge. In this work, a Ni-P hierarchical porous nanoglass (HPNG) catalytic electrode was developed via a low-cost, industrially available electrodeposition technique, which exhibits one of the best performances reported so far in the urea oxidation reaction (UOR), with a potential of 1.330 V at a current density of 10 mA cm^-2 and a Tafel slope of 9.77 mV dec^-1. The superior UOR performance of the HPNG electrode is attributed to the excellent intrinsic catalytic activity of NG with a high-energy state and an extremely enlarged surface area from the unique 3D hierarchical porous structure. Furthermore, a DUFC system with the HPNG anode shows a performance breakthrough as indicated by the maximum power density of 38.15 mW cm^-2 for 0.5 M urea, representing one of the best yet reported DUFCs. Our work demonstrates the feasibility of the scalable production of HPNG electrodes and is expected to be a great contribution to the development of the practical use of DUFCs in the near future for bifunctional energy conversion.