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Collagen Membrane as Water-Based Gel Electrolyte for Electrochromic Devices.
Carmela Tania Prontera1, Nunzia Gallo2, Roberto Giannuzzi1,3
1CNR NANOTEC-Institute of Nanotechnology c/o Campus Ecotekne, University of Salento, Via Monteroni, 73100 Lecce, Italy.
Gels (Basel, Switzerland)
|April 27, 2023
Summary
Cross-linked collagen membranes show promise as bio-based electrolytes for electrochromic devices. These sustainable materials offer good stability and ionic conductivity, paving the way for eco-friendly full-solid-state devices.
Area of Science:
- Materials Science
- Electrochemistry
- Polymer Science
Background:
- Bio-based polymers are increasingly explored as sustainable alternatives to conventional polymers.
- Electrolytes are critical components in electrochemical devices, influencing overall performance.
- Polymers are promising for developing solid-state and gel electrolytes for advanced devices.
Purpose of the Study:
- To fabricate and characterize uncrosslinked and physically cross-linked collagen membranes.
- To evaluate collagen membranes as polymeric matrices for gel electrolytes.
- To assess their potential for use in electrochromic devices.
Main Methods:
- Fabrication and characterization of collagen membranes (uncrosslinked and crosslinked).
- Evaluation of membrane stability in aqueous solutions and mechanical properties.
- Measurement of optical characteristics and ionic conductivity after sulfuric acid treatment.
- Fabrication and testing of a proof-of-concept electrochromic device.
Main Results:
- Cross-linked collagen membranes exhibited a favorable balance of water absorption and resistance.
- The membranes demonstrated suitable optical characteristics and ionic conductivity for electrolyte applications.
- A proof-of-concept electrochromic device using the collagen membrane showed effective optical modulation and kinetics.
Conclusions:
- Physically cross-linked collagen membranes are viable bio-based polymeric matrices for gel electrolytes.
- These membranes show significant potential as electrolytes for full-solid-state electrochromic devices.
- The study highlights collagen as a sustainable material for advanced electrochemical applications.

