Novel Hydrophobic Ultrafiltration Membranes for Treatment of Oil-Contaminated Wastewater

Cutting fluids are the main source of oily wastewater in the metalworking industry. This study deals with the development of antifouling composite hydrophobic membranes for treatment of oily wastewater. The novelty of this study is that a low energy electron-beam deposition technique was applied for a polysulfone (PSf) membrane with a molecular-weight cut-off of 300 kDa, which is promising for use in the treatment of oil-contaminated wastewater, by using polytetrafluoroethylene (PTFE) as target materials. The effect of the thickness of the PTFE layer (45, 660, and 1350 nm) on the structure, composition, and hydrophilicity of membranes was investigated using scanning electron microscopy, water contact angle (WCA) measurements, atomic force microscopy, and FTIR-spectroscopy. The separation and antifouling performance of the reference and modified membranes were evaluated during ultrafiltration of cutting fluid emulsions. It was found that the increase in the PTFE layer thickness results in the significant increase in WCA (from 56° up to 110-123° for the reference and modified membranes respectively) and decrease in surface roughness. It was found that cutting fluid emulsion flux of modified membranes was similar to the flux of the reference PSf-membrane (7.5-12.4 L·m^-2·h^-1 at 6 bar) while cutting fluid rejection (R) of modified membranes increased compared to the reference membrane (R = 58.4-93.3% for modified and R = 13% for the reference PSf membrane). It was established that despite the similar flux of cutting fluid emulsion, modified membranes demonstrate 5-6.5 times higher flux recovery ratio (FRR) compared to the reference membrane. The developed hydrophobic membranes were found to be highly efficient in oily wastewater treatment.