Assessment of PCDD/Fs formation and emission characteristics at a municipal solid waste incinerator for one year

Municipal solid waste incineration (MSWI) has become a predominant emission source of polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs). Research focusing on the impact of operating conditions, environmental changes, and operating time on the generation and emissions of PCDD/Fs has not been resolved. To this end, this study tracked and investigated the PCDD/Fs and 17 congener emissions of a typical grate incinerator (800 t/d) continuously for one year. Results showed that the PCDD/Fs concentration at the boiler outlet, stack inlet, and bag filter, including normal and abnormal operation conditions, ranges from 2.11E-02-41.86 ng I-TEQ/Nm³, 7.00E-04-6.76 ng I-TEQ/Nm³, and 1.12-2.90E+03 ng I-TEQ/Nm³, respectively. The 2,3,4,7,8-P₅CDF has the highest contribution in all samples, in which a proportion of TEQ ranged from 30 % to 77.73 %. Moreover, by applying the correlation analysis between PCDD/Fs and operating parameters, the emission characteristic is mainly affected by incinerators and boilers during the normal period, and it is affected by the whole MSWI process under abnormal conditions. In addition, the PCDD/Fs emission from the MSWI plant gradually increases from spring to winter. This study is beneficial for supporting the control of PCDD/Fs emission reduction and assisting the operators to optimize the relevant operating parameters of the MSWI plant to achieve a stable and up-to-substandard emissions during the operation period.