An Artificial MnWO₄ Cathode Electrolyte Interphase Enabling Enhanced Electrochemical Performance of δ-MnO₂ Cathode...

The dissolution of active material in aqueous batteries can lead to a rapid deterioration in capacity, and the presence of free water can also accelerate the dissolution and trigger some side reactions that affect the service life of aqueous batteries. In this study, a MnWO₄ cathode electrolyte interphase (CEI) layer is constructed on a δ-MnO₂ cathode by cyclic voltammetry, which is effective in inhibiting the dissolution of Mn and improving the reaction kinetics. As a result, the CEI layer enables the δ-MnO₂ cathode to produce a better cycling performance, with the capacity maintained at 98.2% (vs. activated capacity at 500 cycles) after 2000 cycles at 10 A g^-1. In comparison, the capacity retention rate is merely 33.4% for pristine samples in the same state, indicating that this MnWO₄ CEI layer constructed by using a simple and general electrochemical method can promote the development of MnO₂ cathodes for aqueous zinc ion batteries.