Recent Advances in Graphitic Carbon Nitride Based Electro-Catalysts for CO₂ Reduction Reactions

The electrocatalytic carbon dioxide reduction reaction is an effective means of combating the greenhouse effect caused by massive carbon dioxide emissions. Carbon nitride in the graphitic phase (g-C₃N₄) has excellent chemical stability and unique structural properties that allow it to be widely used in energy and materials fields. However, due to its relatively low electrical conductivity, to date, little effort has been made to summarize the application of g-C₃N₄ in the electrocatalytic reduction of CO₂. This review focuses on the synthesis and functionalization of g-C₃N₄ and the recent advances of its application as a catalyst and a catalyst support in the electrocatalytic reduction of CO₂. The modification of g-C₃N₄-based catalysts for enhanced CO₂ reduction is critically reviewed. In addition, opportunities for future research on g-C₃N₄-based catalysts for electrocatalytic CO₂ reduction are discussed.