The Photocatalytic Activity of CaTiO₃ Derived from the Microwave-Melting Heating Process of Blast Furnace Slag

The extraction of titanium-bearing components in the form of CaTiO₃ is an efficient utilization of blast furnace slag. The photocatalytic performance of this obtained CaTiO₃ (MM-CaTiO₃) as a catalyst for methylene blue (MB) degradation was evaluated in this study. The analyses indicated that the MM-CaTiO₃ had a completed structure with a special length-diameter ratio. Furthermore, the oxygen vacancy was easier to generate on a MM-CaTiO₃(110) plane during the photocatalytic process, contributing to improving photocatalytic activity. Compared with traditional catalysts, MM-CaTiO₃ has a narrower optical band gap and visible-light responsive performance. The degradation experiments further confirmed that the photocatalytic degradation efficiency of pollutants by using MM-CaTiO₃ was 3.2 times that of pristine CaTiO₃ in optimized conditions. Combined with molecular simulation, the degradation mechanism clarified that acridine of MB molecular was stepwise destroyed by using MM-CaTiO₃ in short times, which is different from demethylation and methylenedioxy ring degradation by using TiO₂. This study provided a promising routine for using solid waste to obtain catalysts with excellent photocatalytic activity and was found to be in keeping with sustainable environmental development.