High-Rate-Capacity Cathode Based on Zn-Doped and Carbonized Polyacrylonitrile-Coated Na₄MnV(PO₄)₃ for Sodium-Ion...

Na₄MnV(PO₄)₃ (NMVP) is a promising cathode material for sodium-ion batteries (SIBs) because of its extraordinary three-dimensional structure that provides plenty of channels for sodium-ion migration. However, the unsatisfied electrical conductivity of NMVP limits its utilization in SIBs. Herein, Zn-doped NMVP with a uniform carbonized polyacrylonitrile (PAN) coating layer, named NMZVP@cPAN, was synthesized via a sol-gel method, and carbonized PAN was uniformly distributed on the surface of NMVP. Therefore, the NMZVP@cPAN cathodes exhibited an outstanding discharge capacity of 70.6 mA·h·g^-1 at 30 C and remarkable cycling stability with an admirable retention of 89.64% after 1000 cycles at 5 C. Rietveld refinement and ex situ X-ray diffraction analyses were performed to determine the change in the crystal structure. Density functional theory calculations were performed to determine the effects of Zn doping on the density of states and the migration energy barriers. Finally, the NMZVP@cPAN cathodes were successfully modified and could be used in SIBs as NMVP cathodes.