Starch-based porous carbon microsphere composited NiCo₂O₄ nanoflower as bifunctional electrocatalyst for zinc-air...

It is significant to explore and design outstanding bifunctional oxygen electrocatalysts to promote the oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) in zinc-air batteries. Herein, a novel porous carbon microspheres (CMS₂) modified by NiCo₂O₄ nanoflower (CMS₂-NiCo₂O₄) have been prepared as an ORR and OER catalyst. The hierarchical porous structure of CMS provides high conductivity and abundant active sites for ORR, whereas the synergistic effect of NiCo₂O₄ nanosheets and a small amount of FeZn oxides act as the positive phase for OER. The efficient oxygen catalytic activity is gained by creating a coupling interface between NiCo₂O₄ and CMS. The optimized CMS₂-NiCo₂O₄ shows a half-wave potential of 0.82 V toward ORR and an overpotential of 392 mV toward OER. Particularly, CMS₂-NiCo₂O₄ also exhibits an excellent peak power density (175.5 mW cm^-2) as a catalyst for zinc-air batteries, which is superior to the commercial Pt/C + RuO₂ catalyst (120.5 mW cm^-2), and it also demonstrates a remarkable stability even after the charge-discharge cycles of 167 h. The prepared CMS₂-NiCo₂O₄ is promising for the application of the bimetallic oxide catalyst for zinc-air battery.